LiFePO4-based material is considered as one of the most promising for positive electrodes in commercial lithium-ion batteries. However, the reasons for the decrease in their electrical storage specifications during electrochemical cycles are not fully understood. Besides the structural and chemical instabilities of the material itself, surface effects originating from interactions with the electrolyte have to be taken into account.
For instance, the formation of the so-called Solid Electrolyte Interface (SEI) is considered as one of the most important factors defining the overall battery behavior in terms of storage properties, charge transfer kinetics and irreversible capacity loss. Li-ion batteries have a high energy density. The electronic transfers during charge/ discharge cycles are combined with Lithium exchange between electrodes through the electrolyte. Iron phosphates are used for positive electrodes and allows the Lithium to be intercalated or released.
Different synthesis batches of LiFePO4/C materials were prepared and their electrochemical properties as positive cathodes for lithium-ion batteries were evaluated. Using standard solid-state NMR conditions, such as a 7 mm magic-angle-spinning probe performing at low spinning rates, information on both intercalated and non-intercalated (stored on the grain boundaries) lithium was obtained. A sharp signal assigned to non-intercalated lithium could be observed by diluting the active material in silica. Correlations could be thus obtained between the amount of each type of Lithium and the electrochemical history and state of the material, revealing that the relative amount of surface lithium in a pristine LiFePO4/C material is rather constant and cannot be used as a criterion for its further specification. However, a drastic increase of this surface lithium was observed in the cathode materials of out-of-order batteries. As the cathode material recovered from the batteries after electrochemical testing was carefully washed before analysis, we can conclude that the non-intercalated lithium is strongly bound to the active material probably inside the so-called Solid Electrolyte Interface (SEI) layer at the surfaces of LiFePO4 particles. This work illustrates that solid-state Lithium NMR can allow rapid characterization and testing of LiFePO4/C cathode materials.
Thesis presented November 17, 2023 by Thibaut Jousseaume.
Thesis presented December 18, 2020 by Diana Zapata Dominguez. PhD thesis available as a pdf file.
Thesis presented December 22, 2017 by Maxime Boniface. PhD thesis available as a pdf file.
Thesis presented May 10, 2016 by Gilles Brenet. PhD thesis available as a pdf file.
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